(E)-3-(9-Anthr­yl)-1-(4-fluoro­phen­yl)-2-(4-nitro-1H-imidazol-1-yl)prop-2-en-1-one

نویسندگان

  • Xiao-Ling Wang
  • Guang-Zhou Wang
  • Rong-Xia Geng
  • Cheng-He Zhou
چکیده

In the title compound, C(26)H(16)FN(3)O(3), the dihedral angle between the anthryl and fluoro-phenyl groups is 37.8 (1)°. With respect to the imidazolyl group, the twist angles between the imidazolyl group and the anthryl unit and between the imidazoly group and the fluoro-phenyl group are 64.4 (1) and 74.5 (1)°, respectively.

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منابع مشابه

(E)-3-(9-Anthr­yl)-1-(4-fluoro­phen­yl)-2-(1H-1,2,4-triazol-1-yl)prop-2-en-1-one

The C=C double-bond in the title compound, C(25)H(16)FN(3)O, has an E configuration. The dihedral angle between the fluoro-phenyl and triazole rings is 80.57 (2)°.

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(Z)-3-(9-Anthr­yl)-1-(4-bromo­phen­yl)-2-(4-nitro-1H-imidazol-1-yl)prop-2-en-1-one

In the title mol-ecule, C(26)H(16)BrN(3)O(3), the anthracene and benzene mean planes make dihedral angles of 63.79 (2) and 14.67 (2)°, respectively, with the plane of the imidazole ring. In the crystal structure, weak inter-molecular C-H⋯O hydrogen bonds link mol-ecules to form centrosymmetric dimers. Weak π-π stacking inter-actions, with centroid-centroid distances of 3.779 (2) and 3.826 (2) Å...

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(Z)-3-(9-Anthr­yl)-2-(4-nitro-1H-imidazol-1-yl)-1-p-tolyl­prop-2-en-1-one

In the title mol-ecule, C(27)H(19)N(3)O(3), the imidazole and benzene rings make dihedral angles of 64.72 (4) and 64.02 (4)°, respectively, with the anthracene ring system (r.m.s. deviation = 0.043 Å). The nitro group is coplanar with the imidazole ring [dihedral angle = 1.1 (1)°]. The crystal packing is stabilized by weak π-π inter-actions with centroid-centroid distances of 3.7342 (10) and 3....

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(E)-3-(9-Anthr­yl)-1-(4-chloro­phen­yl)-2-(1H-1,2,4-triazol-1-yl)prop-2-en-1-one

In the title compound, C(25)H(16)ClN(3)O, the anthryl and chloro-phenyl substituents are on opposite sides of the triazole ring. The anthryl and benzene mean planes are aligned at 83.35 (2) and 89.09 (2)°, respectively, with respect to the triazole ring.

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(Z)-3-(9-Anthryl)-1-(4-chloro­phen­yl)-2-(4-nitro-1H-imidazol-1-yl)prop-2-en-1-one

In the title compound, C(26)H(16)ClN(3)O(3), the dihedral angle between the anthracene mean plane and imidazole ring is 64.75 (2)°. In the crystal, π-π inter-actions between anthracene fragments lead to the formation of stacks of mol-ecules propagating in [100]. The short distance between the carbonyl groups of symmetry-related molecules [C⋯O = 2.985 (2) Å] indicates the existence of dipole-dip...

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عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010